Direct Air Carbon Capture Using Metal-Organic Frameworks (MOFs): Techno-Economic Performance of Temperature Vacuum Swing Adsorption (TVSA) Systems

Haider Ali; Duraid Uddin; Asad A. Naqvi; Umair Naeem; Nomaan Akhtar; Saqib Shams; Ali Karim

doi:10.36561/ING.28.16

Autores/as

Haider Ali NED University of Engineering and Technology, Pakistán https://orcid.org/0000-0001-8242-3696
Duraid Uddin NED University of Engineering and Technology, Pakistán https://orcid.org/0009-0009-4351-1162
Asad A. Naqvi NED University of Engineering and Technology, Pakistán https://orcid.org/0000-0001-6290-3115
Umair Naeem NED University of Engineering and Technology, Pakistán https://orcid.org/0009-0003-0763-4081
Nomaan Akhtar NED University of Engineering and Technology, Pakistán https://orcid.org/0009-0007-2969-675X
Saqib Shams NED University of Engineering and Technology, Pakistán https://orcid.org/0009-0009-3932-6095
Ali Karim NED University of Engineering and Technology, Pakistán https://orcid.org/0009-0008-0495-0237

DOI:

https://doi.org/10.36561/ING.28.16

Palabras clave:

Captura directa de carbono en aire, adsorción por oscilación de temperatura y vacío, estructura metalorgánica

Resumen

La tecnología de Captura Directa de Carbono en el Aire (DACC) se utiliza para eliminar CO₂ directamente de la atmósfera, lo que contribuye a combatir eficientemente el cambio climático y las emisiones excesivas de gases de efecto invernadero. En este estudio, se realizó un análisis tecnoeconómico de la DACC, incluyendo sus mecanismos de funcionamiento, necesidades energéticas y costes, así como un resumen del estado actual de la investigación. Esta investigación compara dos estructuras metalorgánicas (MOF) líderes —MIL-101(Cr)-PEI-800 y mmen-Mg₂(dobpdc)—, centrándose en su consumo energético, adsorción de CO₂ y coste. Este estudio investiga el rendimiento de estas MOF en un proceso de adsorción por oscilación de temperatura y vacío (TVSA), que varía cíclicamente la temperatura y la presión para capturar CO₂ y regenerar los adsorbentes. Entre todos los materiales, mmen-Mg₂(dobpdc) alcanza el mejor rendimiento, con una capacidad mucho mayor y una forma de isoterma no lineal favorable, lo que indica una eficiencia significativamente mejorada y un menor consumo de energía. Los sistemas DACC basados en MOF avanzados son muy prometedores para minimizar las emisiones de fuentes no puntuales y, por lo tanto, deberían considerarse componentes esenciales de una estrategia de mitigación del cambio climático. Este estudio contribuye a orientar la investigación y el desarrollo futuros hacia MOF más eficientes y rentables en aplicaciones DACC.

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