Fabricación aditiva de óxido cúprico mediante escritura directa con tinta
DOI:
https://doi.org/10.36561/ING.30.3Palabras clave:
Cerámica avanzada, Impresión directa con tinta, Fabricación aditiva, Óxido de cobre, Óxido cúprico, Aglutinante, Cerámica, Cuerpo verde, Cuerpo marrón, Cerámica sinterizada, Análisis de resistividad de cerámica, Suspensión acuosa de aglutinante, Suspensión con partículasResumen
El método DIW ofrece numerosas ventajas, como la creación rápida de prototipos, la rentabilidad, la reducción de residuos en la fabricación y una mayor flexibilidad de diseño. Actualmente es un método de producción popular para materiales de construcción y tiene un gran potencial para materiales porosos y electrónicos. En este estudio, se fabricaron cerámicas porosas de óxido cúprico (CuO) utilizando un método de escritura directa con tinta (DIW) basado en un precursor acuoso cargado con partículas de cobre. La formulación de la tinta se optimizó para lograr una extrusión estable y cuerpos verdes sin grietas, obteniendo una composición final de 68,0 % en peso de Cu, 31,3 % en peso de agua y 0,6 % en peso de CMC. Tras la oxidación y sinterización al aire, las estructuras impresas mostraron una densidad aparente de 3,60 ± 0,20 g cm⁻³ y una porosidad teórica correspondiente de 43,7 ± 0,9 %. La difracción de rayos X confirmó CuO monoclínico casi puro en fase, sin residuos detectables de Cu o Cu₂O. Los componentes impresos exhibieron una microestructura porosa interconectada y una resistividad de cuatro puntas de 10,5 ± 0,3 Ω·m a 25 °C, lo que refleja la influencia de la alta porosidad en el transporte de carga. La ruta de impresión directa con tinta (DIW) demostrada aquí proporciona una vía controlable para producir arquitecturas porosas de CuO con microestructura ajustable y conductividad eléctrica moderada. Estas características sugieren una posible aplicabilidad en filtración de gases, soportes catalíticos y detección electroquímica; sin embargo, aún se requiere una validación a nivel de dispositivo para evaluar completamente su rendimiento funcional.
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